Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на этот ресурс: http://elar.urfu.ru/handle/10995/64659
Полная запись метаданных
Поле DCЗначениеЯзык
dc.contributor.authorKotova, I. Yu.en
dc.contributor.authorSavina, A. A.en
dc.contributor.authorVandysheva, A. I.en
dc.contributor.authorBelov, D. A.en
dc.contributor.authorStefanovich, S. Yu.en
dc.date.accessioned2018-11-14T11:16:10Z-
dc.date.available2018-11-14T11:16:10Z-
dc.date.issued2018-
dc.identifier.citationSynthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals / I. Yu. Kotova, A. A. Savina, A. I. Vandysheva, D. A. Belov, S. Yu. Stefanovich // Chimica Techno Acta. — 2018. — Vol. 5, No. 3. — P. 132-143.en
dc.identifier.issn2409-5613 (Print)-
dc.identifier.issn2411-1414 (Online)-
dc.identifier.urihttp://elar.urfu.ru/handle/10995/64659-
dc.descriptionReceived: 10.10.2018. Accepted: 22.10.2018. Published: 31.10.2018.en
dc.description.abstractA possibility of the triple molybdates formation with both NASICON-like and NaMg3In(MoO4)5 structures in the Ag2MoO4–AMoO4–Ga2(MoO4)3 (A = Mn, Co, Zn, Ni) systems was studied by powder X-ray diffraction analysis. It was established that NASICON-like phases Ag1−xA1−xGa1+x(MoO4)3 are not formed. The triple molybdates AgA3Ga (MoO4)5 (A = Mn, Co, Zn) isostructural to triclinic NaMg3In(MoO4)5 (sp. gr. P1, Z = 2) were synthesized and characterized. The structure of the obtained compounds was refined for AgZn3Ga(MoO4)5 according to the powder data by the Rietveld method. The structure consists of MoO4 tetrahedra, couples of edge-shared M(1)O6 octahedra, and trimers of edge-shared M(2)O6–, M(3)6–and M(4)O6 octahedra, which are linked by the common vertices to form a 3D framework. High-temperature conductivity measurements revealed that the conductivity of AgMn3Ga(MoO4)5 at 500 °C reaches 10–2 S / cm, which is close to one of the known NASICON-type ionic conductors.en
dc.description.sponsorshipThe research was carried out within the state assignment of BINM SB RAS, supported in part by the Russian Foundation for Basic Research (Project No. 17‑03‑00333a).en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherУральский федеральный университетru
dc.relation.ispartofChimica Techno Acta. 2018. Vol. 5. № 3en
dc.subjectTRIPLE MOLYBDATESen
dc.subjectSILVERen
dc.subjectGALLIUMen
dc.subjectSOLID-STATE SYNTHESISen
dc.subjectPOWDER X-RAY DIFFRACTIONen
dc.subjectRIETVELD REFINEMENTen
dc.subjectIONIC CONDUCTIVITYen
dc.titleSynthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metalsen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsihttps://elibrary.ru/item.asp?id=36379497-
dc.identifier.doi10.15826/chimtech.2018.5.3.02-
local.description.firstpage132-
local.description.lastpage143-
local.issue3-
local.volume5-
Располагается в коллекциях:Chimica Techno Acta

Файлы этого ресурса:
Файл Описание РазмерФормат 
cta-2018-3-02.pdf1,03 MBAdobe PDFПросмотреть/Открыть


Все ресурсы в архиве электронных ресурсов защищены авторским правом, все права сохранены.