Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/59666
Title: Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides
Authors: Rotermel, M. V.
Krasnenko, T. I.
Petrova, S. A.
Titova, S. G.
Issue Date: 2018
Publisher: Уральский федеральный университет
Citation: Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides / M. V. Rotermel, T. I. Krasnenko, S. A. Petrova, S. G. Titova // Chimica Techno Acta. — 2018. — Vol. 5, No. 1. — P. 86-91.
Abstract: A new previously unknown effect of a reversible transition from a singlephase system to a heterophase system containing a non-autonomous phase was observed during thermal and chemical deformations of the Zn2–2xCd2xV2O7 structure.The role of local symmetry in the formation of the non-autonomous phase is shown on the basis of X-ray diffraction studies in situ and a comparative crystal-chemical analysis of the structural deformations of isoform monoclinic solid solutions of zinc and copper pyrovanadates with zero volumetric thermal expansion.
Keywords: NON-AUTONOMOUS PHASE
VOLUME THERMAL EXPANSION
M2V2O7
URI: http://hdl.handle.net/10995/59666
RSCI ID: https://elibrary.ru/item.asp?id=35011103
ISSN: 2409-5613 (Print)
2411-1414 (Online)
DOI: 10.15826/chimtech.2018.5.1.06
metadata.dc.description.sponsorship: The work was supported by UB RAS (project 18-10-3-32).
Origin: Chimica Techno Acta. 2018. Vol. 5. № 1
Appears in Collections:Chimica Techno Acta

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