Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/51500
Title: Reactions of 1,1,1-trihalo-3-nitrobut-2-enes with enamines derived from cycloalkanones. Rearrangement of trifluoromethylated 1,2-oxazine N-oxide into 1-pyrroline N-oxides and stereochemistry of the products
Authors: Korotaev, V. Yu.
Barkov, A. Yu.
Slepukhin, P. A.
Sosnovskikh, V. Ya.
Issue Date: 2012
Citation: Reactions of 1,1,1-trihalo-3-nitrobut-2-enes with enamines derived from cycloalkanones. Rearrangement of trifluoromethylated 1,2-oxazine N-oxide into 1-pyrroline N-oxides and stereochemistry of the products / V. Yu. Korotaev, A. Yu. Barkov, P. A. Slepukhin, V. Ya. Sosnovskikh // Russian Chemical Bulletin. — 2012. — Vol. 61. — № 9. — P. 1750-1760.
Abstract: 1,2-Oxazine N-oxides derived from (E)-1,1,1-trifluoro-3-nitrobut-2-ene and cyclohexanone enamines underwent spontaneous rearrangement with ring contraction to give 1-pyrroline N-oxides. Reactions of (E)-1,1,1-trifluoro(trichloro)-3- nitrobut-2-enes with N-cyclopent-enylmorpholine resulted in a series of novel CX3-containing nitroalkyl enamines and g-nitro ketones; the stereochemistry of the synthesized compounds were studied by NMR spectroscopy and X-ray diffraction. © 2012 Springer Science+Business Media New York.
Keywords: Γ-NITRO KETONES
1,1,1-TRIHALO-3-NITROBUT-2-ENES
1,2-OXAZINE N-OXIDES
ENAMINES
ORGANOFLUORINE AND ORGANOCHLORINE COMPOUNDS
X-RAY DIFFRACTION
URI: http://hdl.handle.net/10995/51500
metadata.dc.rights: info:eu-repo/semantics/restrictedAccess
RSCI ID: 21897440
SCOPUS ID: 84887525055
WOS ID: WOS:000321916700010
PURE ID: 1076479
ISSN: 1066-5285
DOI: 10.1007/s11172-012-0241-0
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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