Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/51499
Title: Reactions of (E)-3,3,3-trichloro(trifluoro)-1-nitropropenes with enamines derived from cycloalkanones. A new type of ring-chain tautomerism in a series of cyclobutane derivatives and stereochemistry of the products
Authors: Korotaev, V. Yu.
Barkov, A. Yu.
Sosnovskikh, V. Ya.
Issue Date: 2012
Citation: Korotaev V. Yu. Reactions of (E)-3,3,3-trichloro(trifluoro)-1-nitropropenes with enamines derived from cycloalkanones. A new type of ring-chain tautomerism in a series of cyclobutane derivatives and stereochemistry of the products / V. Yu. Korotaev, A. Yu. Barkov, V. Ya. Sosnovskikh // Russian Chemical Bulletin. — 2012. — Vol. 61. — № 9. — P. 1736-1749.
Abstract: Depending on the reaction conditions, the reactions of (E)-3,3,3-trichloro- 1-nitropropene with cyclohexanone enamines led to bicyclo[4.2.0]octanes or trisubstituted enamines, which are the ring-chain tautomers capable of reversible transformations. Diastereoselectivity of the reactions of (E)-3,3,3-trichloro(trifluoro)-1-nitropropenes with cycloalkanone enamines were studied, a series of hitherto unknown CX3-containing nitroalkylated enamines and γ-nitro ketones were synthesized, the structures of novel compounds were determined by NMR spectroscopy and X-ray diffraction. © 2012 Springer Science+Business Media New York.
Keywords: Γ-NITRO KETONES
3,3,3-TRIHALO-1-NITROPROPENES
CYCLOBUTANES
ENAMINES
ORGANOFLUORINE AND ORGANOCHLORINE COMPOUNDS
X-RAY DIFFRACTION
URI: http://hdl.handle.net/10995/51499
metadata.dc.rights: info:eu-repo/semantics/restrictedAccess
RSCI ID: 21897359
SCOPUS ID: 84887380528
WOS ID: WOS:000321916700009
PURE ID: 1076074
ISSN: 1066-5285
DOI: 10.1007/s11172-012-0240-1
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

Files in This Item:
File Description SizeFormat 
10.1007s11172-012-0240-1_2012.pdf623,88 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.