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Полная запись метаданных
Поле DC | Значение | Язык |
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dc.contributor.author | Seredin, P. | en |
dc.contributor.author | Goloshchapov, D. | en |
dc.contributor.author | Buylov, N. | en |
dc.contributor.author | Kashkarov, V. | en |
dc.contributor.author | Emelyanova, A. | en |
dc.contributor.author | Eremeev, K. | en |
dc.contributor.author | Ippolitov, Y. | en |
dc.date.accessioned | 2024-04-08T11:06:52Z | - |
dc.date.available | 2024-04-08T11:06:52Z | - |
dc.date.issued | 2022 | - |
dc.identifier.citation | Seredin, P, Goloshchapov, D, Buylov, N, Kashkarov, V, Emelyanova, A, Eremeev, K & Ippolitov, Y 2022, 'Compositional Analysis of the Dental Biomimetic Hybrid Nanomaterials Based on Bioinspired Nonstoichiometric Hydroxyapatite with Small Deviations in the Carbonate Incorporation', Nanomaterials, Том. 12, № 24, 4453. https://doi.org/10.3390/nano12244453 | harvard_pure |
dc.identifier.citation | Seredin, P., Goloshchapov, D., Buylov, N., Kashkarov, V., Emelyanova, A., Eremeev, K., & Ippolitov, Y. (2022). Compositional Analysis of the Dental Biomimetic Hybrid Nanomaterials Based on Bioinspired Nonstoichiometric Hydroxyapatite with Small Deviations in the Carbonate Incorporation. Nanomaterials, 12(24), [4453]. https://doi.org/10.3390/nano12244453 | apa_pure |
dc.identifier.issn | 2079-4991 | - |
dc.identifier.other | Final | 2 |
dc.identifier.other | All Open Access; Gold Open Access; Green Open Access | 3 |
dc.identifier.other | https://www.mdpi.com/2079-4991/12/24/4453/pdf?version=1671075330 | 1 |
dc.identifier.other | https://www.mdpi.com/2079-4991/12/24/4453/pdf?version=1671075330 | |
dc.identifier.uri | http://elar.urfu.ru/handle/10995/131358 | - |
dc.description.abstract | In our paper, we discuss the results of a comprehensive structural-spectroscopic and microscopic analysis of non-stoichiometric nanocrystalline hydroxyapatite (CHAp) with low carbonate anion content and biomimetic hybrid nanomaterials produced on its basis. It was shown that hydroxyapatite nanocrystals synthesized by chemical precipitation and biogenic calcium source mimic the properties of biogenic apatite and also have a morphological organization of “core–shell” type. The “core” of the CHAp nanocrystal is characterized by an overabundance of calcium Ca/P~1.9. Thus “a shell” with thickness of ~3–5 nm is formed from intermediate apatite-like phases where the most probable are octocalcium phosphate, dicalcium phosphate dihydrate and tricalcium phosphate. The multimode model of the Raman profile of samples CHAp and biomimetic composites for spectral region 900–1100 cm−1 proposed in our work has allowed to allocate precise contribution of B-type carbonate substitution, taking into account the presence on a surface of “core” HAp nanocrystal of various third-party intermediate apatite-like phases. The calibration function constructed on the basis of the described model makes it possible to reliably determine small concentrations of carbonate in the structure of hydroxyapatite with the application of Raman express method of diagnostics. The results of our work can inspire researchers to study the processes of induced biomineralization in mineralized tissues of the human body, using non-destructive methods of control with simultaneous analysis of chemical bonding, as well as determining the role of impurity atoms in the functions exhibited by biotissue. © 2022 by the authors. | en |
dc.description.sponsorship | Russian Science Foundation, RSF, (21-75-10005) | en |
dc.description.sponsorship | This work was funded by the grant of Russian Science Foundation, grant number 21-75-10005. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | en | en |
dc.publisher | MDPI | en |
dc.relation | info:eu-repo/grantAgreement/RSF//21-75-10005 | en |
dc.rights | info:eu-repo/semantics/openAccess | en |
dc.rights | cc-by | other |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | unpaywall |
dc.source | Nanomaterials | 2 |
dc.source | Nanomaterials | en |
dc.subject | BIOMIMETIC HYBRID NANOMATERIALS | en |
dc.subject | CARBONATE ANION | en |
dc.subject | MULTIMODE RAMAN PROFILE MODEL | en |
dc.subject | NON-STOICHIOMETRIC NANOCRYSTALLINE HYDROXYAPATITE | en |
dc.title | Compositional Analysis of the Dental Biomimetic Hybrid Nanomaterials Based on Bioinspired Nonstoichiometric Hydroxyapatite with Small Deviations in the Carbonate Incorporation | en |
dc.type | Article | en |
dc.type | info:eu-repo/semantics/article | en |
dc.type | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.3390/nano12244453 | - |
dc.identifier.scopus | 85144836526 | - |
local.contributor.employee | Seredin P., Solid State Physics and Nanostructures Department, Voronezh State University, Universitetskaya Pl. 1, Voronezh, 394018, Russian Federation, Scientific and Educational Center, Nanomaterials and Nanotechnologies, Ural Federal University, Lenin Ave 51, Yekaterinburg, 620002, Russian Federation | en |
local.contributor.employee | Goloshchapov D., Solid State Physics and Nanostructures Department, Voronezh State University, Universitetskaya Pl. 1, Voronezh, 394018, Russian Federation | en |
local.contributor.employee | Buylov N., Solid State Physics and Nanostructures Department, Voronezh State University, Universitetskaya Pl. 1, Voronezh, 394018, Russian Federation | en |
local.contributor.employee | Kashkarov V., Solid State Physics and Nanostructures Department, Voronezh State University, Universitetskaya Pl. 1, Voronezh, 394018, Russian Federation | en |
local.contributor.employee | Emelyanova A., Solid State Physics and Nanostructures Department, Voronezh State University, Universitetskaya Pl. 1, Voronezh, 394018, Russian Federation | en |
local.contributor.employee | Eremeev K., Solid State Physics and Nanostructures Department, Voronezh State University, Universitetskaya Pl. 1, Voronezh, 394018, Russian Federation | en |
local.contributor.employee | Ippolitov Y., Department of Pediatric Dentistry with Orthodontia, Voronezh State Medical University, Studentcheskaya Ul. 11, Voronezh, 394006, Russian Federation | en |
local.issue | 24 | - |
local.volume | 12 | - |
dc.identifier.wos | 000902808400001 | - |
local.contributor.department | Solid State Physics and Nanostructures Department, Voronezh State University, Universitetskaya Pl. 1, Voronezh, 394018, Russian Federation | en |
local.contributor.department | Scientific and Educational Center, Nanomaterials and Nanotechnologies, Ural Federal University, Lenin Ave 51, Yekaterinburg, 620002, Russian Federation | en |
local.contributor.department | Department of Pediatric Dentistry with Orthodontia, Voronezh State Medical University, Studentcheskaya Ul. 11, Voronezh, 394006, Russian Federation | en |
local.identifier.pure | 33224213 | - |
local.identifier.pure | dee15f84-2c6c-4c12-aac9-28c21e43f458 | uuid |
local.description.order | 4453 | - |
local.identifier.eid | 2-s2.0-85144836526 | - |
local.fund.rsf | 21-75-10005 | - |
local.identifier.wos | WOS:000902808400001 | - |
Располагается в коллекциях: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
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2-s2.0-85144836526.pdf | 38,44 MB | Adobe PDF | Просмотреть/Открыть |
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