1. Электронный научный архив УрФУ
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  3. Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC
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dc.contributor.authorVolchek, V. V.en
dc.contributor.authorBerezin, A. S.en
dc.contributor.authorSokolov, M. N.en
dc.contributor.authorAbramov, P. A.en
dc.date.accessioned2024-04-08T11:05:49Z-
dc.date.available2024-04-08T11:05:49Z-
dc.date.issued2022-
dc.identifier.citationVolchek, VV, Berezin, AS, Sokolov, MN & Abramov, PA 2022, 'Stabilization of {Ag20(StBu)10} and {Ag19(StBu)10} Toroidal Complexes in DMSO: HPLC-ICP-AES, PL, and Structural Studies', Inorganics, Том. 10, № 12, 225. https://doi.org/10.3390/inorganics10120225harvard_pure
dc.identifier.citationVolchek, V. V., Berezin, A. S., Sokolov, M. N., & Abramov, P. A. (2022). Stabilization of {Ag20(StBu)10} and {Ag19(StBu)10} Toroidal Complexes in DMSO: HPLC-ICP-AES, PL, and Structural Studies. Inorganics, 10(12), [225]. https://doi.org/10.3390/inorganics10120225apa_pure
dc.identifier.issn2304-6740-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access; Gold Open Access3
dc.identifier.otherhttps://www.mdpi.com/2304-6740/10/12/225/pdf?version=16694508761
dc.identifier.otherhttps://www.mdpi.com/2304-6740/10/12/225/pdf?version=1669450876pdf
dc.identifier.urihttp://elar.urfu.ru/handle/10995/131216-
dc.description.abstractThe presence of DMSO provides a unique ability to stabilize silver toroidal complexes in the direct reaction between AgStBu and AgNO3 at 80 °C. Slow cooling results in large crystals of [NO3@Ag19.2(StBu)10(DMSO)5.2(NO3)8.2]·3DMSO (1), which were isolated and characterized by single crystal X-ray diffraction (SCXRD) analysis. The crystal structure contains both {Ag20(StBu)10} and {Ag19(StBu)10} clusters. The solution of these material in DMSO was studied with HPLC techniques, which demonstrated the presence of both complexes in solution. The use of [SiW12O40]4– as counter anion gives crystals of a double complex salt [Ag17.8(NO3)3.8(StBu)10][SiW12O40]·30DMSO (2) under the same conditions. Temperature-dependent photoluminescence (PL) was studied. © 2022 by the authors.en
dc.description.sponsorshipCouncil on grants of the President of the Russian Federation, (MD-396.2021.1.3)en
dc.description.sponsorshipThis work was supported by the grant of the President of the Russian Federation for young scientists—Doctors of sciences MD-396.2021.1.3.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherMDPIen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.rightscc-byother
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/unpaywall
dc.sourceInorganics2
dc.sourceInorganicsen
dc.subjectASSOCIATIONen
dc.subjectCHROMATOGRAPHYen
dc.subjectPHOTOLUMINESCENCEen
dc.subjectSILVER THIOLATEen
dc.subjectSTRUCTURAL ANALYSISen
dc.titleStabilization of {Ag20(StBu)10} and {Ag19(StBu)10} Toroidal Complexes in DMSO: HPLC-ICP-AES, PL, and Structural Studiesen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.3390/inorganics10120225-
dc.identifier.scopus85144705301-
local.contributor.employeeVolchek V.V., Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave, Novosibirsk, 630090, Russian Federationen
local.contributor.employeeBerezin A.S., Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave, Novosibirsk, 630090, Russian Federationen
local.contributor.employeeSokolov M.N., Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave, Novosibirsk, 630090, Russian Federationen
local.contributor.employeeAbramov P.A., Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave, Novosibirsk, 630090, Russian Federation, Institute of Natural Sciences and Mathematics, Ural Federal University Named after B.N. Yeltsin, Yekaterinburg, 620075, Russian Federationen
local.issue12-
local.volume10-
dc.identifier.wos000901008200001-
local.contributor.departmentNikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave, Novosibirsk, 630090, Russian Federationen
local.contributor.departmentInstitute of Natural Sciences and Mathematics, Ural Federal University Named after B.N. Yeltsin, Yekaterinburg, 620075, Russian Federationen
local.identifier.pure33222263-
local.identifier.pured13ba15d-ee83-417c-bac8-2a9554cd3e63uuid
local.description.order225-
local.identifier.eid2-s2.0-85144705301-
local.identifier.wosWOS:000901008200001-
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